Dr. James Franklin Hyde

Another very early attempt at a spiral treatment was done by J. F. Hyde of Dow Corning Corporation in 1975.See also the closeup of the low atomic number elements shows that his chart is missing the first bifurcation in my chart.

James Franklin Hyde - Hall of Fame Entry
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James Franklin Hyde - Hall of Fame Entry
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James Franklin Hyde
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To the employees of Dow Corning Corporation, which was his laboratory and home base for more than 40 years, Dr. Hyde is recognized as the "Father of Industrial Silicone Chemistry" and designer of the Chemical Elements Periodic Table.

In 1931, Dr. Hyde became the first organic chemist to be employed by Corning Glass Works.His assignment was to see what might be done by the glass industry to meet the challenge imposed by the newly introduced transparent plastics.
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Throughout his career, Dr. Hyde's fundamental research has habitually opened up new areas of practical application.He demonstrated new concepts of polymerization and depolymerization of linear polymers and laid the foundation for the present process in silicone high polymer production.He later formulated a silicone rubber that would vulcanize at room temperature.The rubber is now used in such diverse applications as dental-impression materials, encapsulation of electronic equipment, and caulking compounds for windows and bathtubs.

Medical applications for silicones developed by Dr. Hyde embrace the entire body, from the molding of prosthetic heart valves to repairing detached retinas.

Dr. Hyde was born in Solvay, NY, in 1903.He earned his Bachelor of Arts and Master of Arts degrees at Syracuse University.At the University of Illinois, he earned a PhD in organic chemistry.He then achieved a post-doctoral fellowship at Harvard University under Dr. James Bryant Conant.

Dr. Hyde's career with the Dow Corning Corporation spans four decades.From his initial post as a research chemist, he next became manager of the Organic Chemistry Research Laboratory, a position he held from 1938 to 1951.From 1951 until his retirement in 1973, Dr. Hyde was senior research scientist for basic organosilicon chemistry.He then became a research consultant to Dow Corning.

Among the many honors bestowed on Dr. Hyde are Doctor of Science (Honorary), Syracuse University; Perkin Medal, awarded by the American Section of the Society of Chemical Industry (United Kingdom); and the J.B. Whitehead Award from the National Academy of Sciences.

Let's begin to list the chemical concepts you will reinforce in this silicone rubber unit: Dr. Dr. A young, Harvard trained chemist, Dr. James Franklin Hyde, working for Corning, recognized the need for a C2H5)2SiCl2(4) had produced "glue like" materials when Kipping had treated
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A young, Harvard trained chemist, Dr. James Franklin Hyde, working for Corning, recognized the need for a C2H5)2SiCl2(4) had produced "glue like" materials when Kipping had treated

James Franklin Hyde - Hall of Fame Entry | Read Full Article Plastics Academy Hall of Fame :: http://www.plasticsacademy.org - powered by plastics.com
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James Franklin Hyde - Hall of Fame Entry
...
James Franklin Hyde - Hall of Fame Entry
...
James Franklin Hyde
...
To the employees of Dow Corning Corporation, which was his laboratory and home base for more than 40 years, Dr. Hyde is recognized as the "Father of Industrial Silicone Chemistry" and designer of the Chemical Elements Periodic Table.

In 1931, Dr. Hyde became the first organic chemist to be employed by Corning Glass Works. His assignment was to see what might be done by the glass industry to meet the challenge imposed by the newly introduced transparent plastics.
...
Throughout his career, Dr. Hyde's fundamental research has habitually opened up new areas of practical application. He demonstrated new concepts of polymerization and depolymerization of linear polymers and laid the foundation for the present process in silicone high polymer production. He later formulated a silicone rubber that would vulcanize at room temperature. The rubber is now used in such diverse applications as dental-impression materials, encapsulation of electronic equipment, and caulking compounds for windows and bathtubs.

Medical applications for silicones developed by Dr. Hyde embrace the entire body, from the molding of prosthetic heart valves to repairing detached retinas.

Dr. Hyde was born in Solvay, NY, in 1903. He earned his Bachelor of Arts and Master of Arts degrees at Syracuse University. At the University of Illinois, he earned a PhD in organic chemistry. He then achieved a post-doctoral fellowship at Harvard University under Dr. James Bryant Conant.

Dr. Hyde's career with the Dow Corning Corporation spans four decades. From his initial post as a research chemist, he next became manager of the Organic Chemistry Research Laboratory, a position he held from 1938 to 1951. From 1951 until his retirement in 1973, Dr. Hyde was senior research scientist for basic organosilicon chemistry. He then became a research consultant to Dow Corning.

Among the many honors bestowed on Dr. Hyde are Doctor of Science (Honorary), Syracuse University; Perkin Medal, awarded by the American Section of the Society of Chemical Industry (United Kingdom); and the J.B. Whitehead Award from the National Academy of Sciences.

James Franklin Hyde - Hall of Fame Entry | Read Full Article Plastics Academy Hall of Fame :: http://www.plasticsacademy.org - powered by plastics.com
...
James Franklin Hyde - Hall of Fame Entry
...
James Franklin Hyde - Hall of Fame Entry
...
James Franklin Hyde
...
To the employees of Dow Corning Corporation, which was his laboratory and home base for more than 40 years, Dr. Hyde is recognized as the "Father of Industrial Silicone Chemistry" and designer of the Chemical Elements Periodic Table.

In 1931, Dr. Hyde became the first organic chemist to be employed by Corning Glass Works. His assignment was to see what might be done by the glass industry to meet the challenge imposed by the newly introduced transparent plastics.
...
Throughout his career, Dr. Hyde's fundamental research has habitually opened up new areas of practical application. He demonstrated new concepts of polymerization and depolymerization of linear polymers and laid the foundation for the present process in silicone high polymer production. He later formulated a silicone rubber that would vulcanize at room temperature. The rubber is now used in such diverse applications as dental-impression materials, encapsulation of electronic equipment, and caulking compounds for windows and bathtubs.

Medical applications for silicones developed by Dr. Hyde embrace the entire body, from the molding of prosthetic heart valves to repairing detached retinas.

Dr. Hyde was born in Solvay, NY, in 1903. He earned his Bachelor of Arts and Master of Arts degrees at Syracuse University. At the University of Illinois, he earned a PhD in organic chemistry. He then achieved a post-doctoral fellowship at Harvard University under Dr. James Bryant Conant.

Dr. Hyde's career with the Dow Corning Corporation spans four decades. From his initial post as a research chemist, he next became manager of the Organic Chemistry Research Laboratory, a position he held from 1938 to 1951. From 1951 until his retirement in 1973, Dr. Hyde was senior research scientist for basic organosilicon chemistry. He then became a research consultant to Dow Corning.

Among the many honors bestowed on Dr. Hyde are Doctor of Science (Honorary), Syracuse University; Perkin Medal, awarded by the American Section of the Society of Chemical Industry (United Kingdom); and the J.B. Whitehead Award from the National Academy of Sciences.

James Franklin Hyde - Hall of Fame Entry
...
James Franklin Hyde - Hall of Fame Entry
...
James Franklin Hyde
...
To the employees of Dow Corning Corporation, which was his laboratory and home base for more than 40 years, Dr. Hyde is recognized as the "Father of Industrial Silicone Chemistry" and designer of the Chemical Elements Periodic Table.

In 1931, Dr. Hyde became the first organic chemist to be employed by Corning Glass Works.His assignment was to see what might be done by the glass industry to meet the challenge imposed by the newly introduced transparent plastics.
...
Throughout his career, Dr. Hyde's fundamental research has habitually opened up new areas of practical application.He demonstrated new concepts of polymerization and depolymerization of linear polymers and laid the foundation for the present process in silicone high polymer production.He later formulated a silicone rubber that would vulcanize at room temperature.The rubber is now used in such diverse applications as dental-impression materials, encapsulation of electronic equipment, and caulking compounds for windows and bathtubs.

Medical applications for silicones developed by Dr. Hyde embrace the entire body, from the molding of prosthetic heart valves to repairing detached retinas.

Dr. Hyde was born in Solvay, NY, in 1903.He earned his Bachelor of Arts and Master of Arts degrees at Syracuse University.At the University of Illinois, he earned a PhD in organic chemistry.He then achieved a post-doctoral fellowship at Harvard University under Dr. James Bryant Conant.

Dr. Hyde's career with the Dow Corning Corporation spans four decades.From his initial post as a research chemist, he next became manager of the Organic Chemistry Research Laboratory, a position he held from 1938 to 1951.From 1951 until his retirement in 1973, Dr. Hyde was senior research scientist for basic organosilicon chemistry.He then became a research consultant to Dow Corning.

Among the many honors bestowed on Dr. Hyde are Doctor of Science (Honorary), Syracuse University; Perkin Medal, awarded by the American Section of the Society of Chemical Industry (United Kingdom); and the J.B. Whitehead Award from the National Academy of Sciences.

James Franklin Hyde - Hall of Fame Entry

A young, Harvard trained chemist, Dr. James Franklin Hyde, working for Corning, recognized the need for a flexible, high temperature binder for the glass fibers which would allow yet another increase in service temperature for insulating materials. He knew Si-C bonds were stable to heat. He knew Kipping's work on organic silicon chemistry. He was particularly intrigued by Kipping's remark that diethyldichlorosilane (C 2 H 5 ) 2 SiCl 2 (4) had produced "glue like" materials when Kipping had treated it with water. Hyde believed what Kipping had done could be approximated with the chemical reaction:
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Structure (6) , Hyde reasoned was a long sequence of connected Si-O units as shown above. He used his previous chemical knowledge and envisioned changing one of the groups of atoms attached to the silicon atom from -C 2 H 5 to something he expected would make the product resin-like rather than glue-like.

Hyde began an arduous chemical synthesis. His goal was another dichlorosilane similar to (4) calledethylphenyldichlorosilane (C 6 H 5 )(C 2 H 5 )SiCl 2 (7). Recall that Kipping made his organic silicon compounds using Grignard's magnesium-containing reagent. Hyde made two Grignard reagents and carried out this sequence of chemical reactions:

(C 6 H 5 )MgBr + SiCl 4 --> (C 6 H 5 )SiCl 3 + MgClBr

(C 2 H 5 )MgBr + (C 6 H 5 )SiCl 3 --> (C 6 H 5 )(C 2 H 5 )SiCl 2 (7) + MgClBr

When Hyde treated (7) with water, he made a molasses-like fluid he believed was (8):