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Last Visited: 4/28/2007
As Applied Materials Fellow Reza Arghavani explained, it's difficult to achieve consistent grain structure and orientation in such small areas, while even small variations in structure can affect electrical performance.
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As Arghavani put it, "the leading companies know what the answer is [for pMOS], but they aren't saying."Noble metals, such as platinum and iridium, have the desired work function and temperature tolerance, but are notoriously difficult to etch.Conductive oxides, such as iridium oxide, are unstable at high temperatures.
In metal-gate structures, as in polysilicon structures, there is a tendency for the effective work function to drift toward the middle of the band gap after anneal.Annealing in an oxidizing ambient reduces the work-function shift, again indicating oxygen vacancies in the dielectric as a possible cause [3].Arghavani pointed out that many metal integration difficulties might actually be resolved by the use of a replacement-gate scheme.Dual-metal schemes lose many of the advantages of a gate-first structure, as the first metal must be etched away before the second metal is deposited, potentially damaging the silicon (see Fig.1).